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Geospatial Knowledge Graphs (GeoKGs) represent a significant advancement in the integration of AI-driven geographic information, facilitating interoperable and semantically rich geospatial analytics across various domains. This paper explores the use of topologically enriched GeoKGs, built on an explicit representation of S2 Geometry alongside precomputed topological relations, for constructing efficient geospatial analysis workflows within and across knowledge graphs (KGs). \r\nUsing the SAWGraph knowledge graph as a case study focused on enviromental contamination by PFAS, we demonstrate how this framework supports fundamental GIS operations - such as spatial filtering, proximity analysis, overlay operations and network analysis - in a GeoKG setting while allowing for the easy linking of these operations with one another and with semantic filters. This enables the efficient execution of complex geospatial analyses as semantically-explicit queries and enhances the usability of geospatial data across graphs. Additionally, the framework eliminates the need for explicit support for GeoSPARQL’s topological operations in the utilized graph databases and better integrates spatial knowledge into the overall semantic inference process supported by RDFS and OWL ontologies.